In pure PoS systems, new coins only go to existing coin holders. In a hybrid system like Peercoin, PoW injects a small amount of new coins every year into the ecosystem outside of existing holders. These new coins are sold on exchanges by miners and can go to new holders, rather than existing holders.
This continual distribution improves the decentralization of the network over time as it creates new minters that can provide security for the network. Pure PoS has no inherent mechanism to improve distribution and decentralization except hoping existing holders sell their coins on exchanges to new holders.
Also, pure PoS coins are subject to the nothing at stake attack. Our vision for Peercoin and a fix for nothing at stake is letting the majority of blocks come from PoS minters while a minority come from PoW miners, which will inject some entropy into the system. Here are a couple quotes from our core developer @hrobeers…